关键词: 电感耦合等离子体-质谱法；乳粉；铝含量；控制图；评估

Abstract: Inductively coupled plasma-mass spectrometry (ICP-MS) was used to measure the aluminum content in the quality control sample of milk powder, and an X-control chart was established for runaway judgement and handling during the operation process. The precision and median line of the control chart for new data points obtained one year later were evaluated using Minitab software with test for equal variance and analysis of variance. The standard deviation for the previous 25 data points was 0.186 mg/kg compared to 0.126 mg/kg for the 35 new ones, while the median values of the two groups did not differ from each other. More reliable control limit was calculated based on all the data points, and the new median value was 1.334 mg/kg with a standard deviation of 0.154 mg/kg. The decrease in standard deviation suggested that the precision was improved with smaller data fluctuations. In conclusion, calculation of new and more reliable control limit from more data is useful to find obvious systematic errors, abnormal data and slow changing trend in a timely and effective way and can provide evidence to decide whether data should be retained or removed so as to directly reflect the stability and tendency of the detection.

Key words: inductively coupled plasma-mass spectrometry; milk powder; aluminum content; control chart; assessment