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基于气相型电子鼻研究不同脂肪含量牛奶贮藏期间风味变化特征

张珊1,李雯1,张玉婷1,魏雪彤1,孙莹1,薛璐1,赵培1,牛天娇2   

  1. 1. 天津商业大学
    2. 蒙牛鲜乳制品有限公司
  • 收稿日期:2024-04-25 修回日期:2024-06-13 出版日期:2024-05-01 发布日期:2024-08-26
  • 通讯作者: 薛璐
  • 基金资助:
    天津市大学生创新创业训练计划项目

Analysis of Flavor Changes of Milk with Different Fat Content during Storage Using Gas-Phase Electronic Nose

  • Received:2024-04-25 Revised:2024-06-13 Published:2024-05-01 Online:2024-08-26

摘要: 牛乳储藏过程中,牛乳中的脂肪易随贮藏条件变化而发生不同程度的氧化分解,进而改变牛乳香气成分。本研究结合气相型电子鼻检测和感官评价对比了巴氏杀菌全脂乳、低脂乳和脱脂乳在不同贮藏温度和时间的挥发性风味化合物和感官特性变化。结果表明:上述三类牛乳产品在4°C冷藏条件下保持了良好的风味特征。脂肪氧化的难易程度顺序为全脂乳>低脂乳>脱脂乳。全脂乳表现为风味物质更为复杂,共鉴定出43种挥发性化合物,贮藏期未观察到明显的陈腐味。脱脂乳和低脂乳都检测到了脂质氧化的标志物壬醛。脱脂乳更容易出现脂肪的氧化分解,在其贮藏期检测到了2-丁酮、2,3-丁二酮、2-己酮、2-庚酮、2-十一烷酮等脂质氧化的甲基酮类物质。人工感官评价结果与电子鼻的检测结果基本一致,全脂乳甜味和奶香味较为突出,在贮藏期内低脂乳形成的风味最为寡淡,脱脂乳在25℃贮藏21天可感受到轻微的苦味。本研究为监测牛乳产品贮藏期风味变化,提升产品品质提供科学依据。

关键词: 牛乳, 气相型电子鼻, 脂肪氧化, 挥发性成分, 贮藏

Abstract: In the process of milk storage, the fat in milk is easy to oxidize and decompose to different degrees with the change of storage conditions, and then change the aroma components of milk. In this study, Gas-Phase Electronic Nose detection and sensory evaluation were used to compare the changes of volatile flavor compounds and sensory properties of pasteurized whole milk, low-fat milk and skim milk at different storage temperature and time. The results showed that the above three kinds of milk products maintained good flavor characteristics under the condition of 4 °C refrigeration. The order of difficulty of fat oxidation was whole milk > low fat milk > skim milk. The flavor substances of whole milk were more complex, a total of 43 volatile compounds were identified, and no obvious rotten flavor was observed during storage. Nonanal, a marker of lipid oxidation, was detected in both skim milk and low-fat milk. Skim milk was more prone to oxidative decomposition of fat, and lipid-oxidized methyl ketones such as 2-butanone, 2-butanedione, 2-hexanone, 2-heptanone and 2-undecanone were detected during storage. The results of artificial sensory evaluation were basically consistent with those of electronic nose, the sweetness and flavor of whole milk were more prominent, the flavor of low-fat milk was the lightest during storage, and skim milk could feel slight bitterness when stored at 25 ℃ for 21 days. This study will provide a scientific basis for monitoring the flavor changes of milk products during storage and improving the quality of milk products.

Key words: milk, Gas-Phase Electronic Nose, fat oxidation, volatile components, storage